Jon, I think you're misunderstanding the point of the "No Deployment on Friday" policy.
Let's look from far, Why is a work day a no-deploy day? Why are we limiting ourselves to a four-day week while we can use our full potential? The reason is that if we deploy something to production on Friday and if it breaks production, then there is no one around to fix the issue over the weekend. So far it's rather obvious.
In other words, the requirement for having a time to deploy changes is to have some buffer until the weekend *to fix issues caused by changes deployed*. That buffer is Friday. It's made a no deployment day so you could push urgent fixes (including train blockers). Of course, the fix should not be too big to cause issues later.
Fridays are not "no deployment day" in the same of sense Sunday is a "no deployment day". It's the buffer to fix UBN issues, not a long weekend. If you're fixing an UBN issue, then please go ahead and deploy on Friday. The ultimate goal of RelEng policies is to have major issues live in production for the shortest possible time. Refusing to deploy a major fix on a Friday does the exact opposite of that.
Regarding Catalan and Hebrew Wikipedia, the other Amir said it well, I don't think I have much to add beside the fact that I have personally seen them finding major issues before they hit all Wikipedia languages many times, more than I can count.
HTH