Perhaps I am wrong, but I think you will need to program an Extension.
The following Syntax will NOT work:
[http://ix.de [[File:2009-06-04_pic.png]]]
I have take more than 20 minutes to search http://www.mediawiki.org/wiki/Manual:Configuration_settings but I could not find anything to - use external images - create external hyperlinks with thumbnails
Therefore you have to write your own extension, which should not be too hard in this matter.
http://www.mediawiki.org/wiki/Manual:Extensions
Regards, Claus
PS: If you have never written an Extension, here is a short example:
--- $wgExtensionFunctions[] = 'example';
function example() { global $wgParser; $wgParser->setHook('example', 'process_input'); }
function process_input($input, $args, $parser) { return 'Hello World! Your input: ' . htmlspecialchars($input); } ---
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